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摘要
A novel acid/base-co-catalyzed direct intermolecular alpha-amination of various cyclic ketones has been developed for the first time. The reaction employs molecular oxygen as the sole oxidant under metal-free conditions. The reaction tolerates a wide range of various anilines, especially primary diamine derivatives, and provides a simple and efficient method for the constructions of alpha-amino enones and benzodiazepine derivatives in a single step.
- 出版日期2018-2-1
- 单位东北师范大学
