A Computational Meta-Analysis of UCl3 Cyclic Voltammograms in LiCl-KCl Electrolyte

作者:Cumberland Riley M*; Yim Man Sung
来源:Journal of the Electrochemical Society, 2014, 161(4): D147-D149.
DOI:10.1149/2.033404jes

摘要

As a way to characterize the values of key parameters for modeling electrochemical transport of elements in a molten salt system, a meta-analysis of CV reduction peaks for UCl3 in LiCl-KCl eutectic was performed. Published CV data was fit using least squares fitting software coupled with electrochemical simulation software. The analysis yielded estimates of apparent standard potential, the diffusion coefficient, and the exchange current density for each reaction. The results for the UCl3 reduction peak matched well with existing data.

  • 出版日期2014