科研之友
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摘要
The iridoid natural products iridomyrmecin, isoiridomyrmecin, teucriumlactone, and dolicholactone were prepared from citronellol using a divergent diastereoselective approach. Key steps include a highly diastereoselective enarnine/enal cycloaddition and the selective reduction of masked aldehyde functionalities by ionic hydrogenation.
