Ammonolysis of magnesiothermic tantalum powders

作者:Orlov V M*; Kuznetsov V Ya; Osaulenko R N
来源:Russian Journal of Inorganic Chemistry, 2017, 62(1): 33-38.
DOI:10.1134/S0036023617010132

摘要

Tantalum nitrides are synthesized by ammonolysis of a mesoporous magnesiothermic tantalum powders. The effect of specific surface area of the powders and synthesis temperature on product composition is shown. Nitrogen content in the ammonolysis product of tantalum powder with a specific surface area of 56 m(2) g(-1) corresponds to oxynitride TaON exposed to 600A degrees C for 1 h. The specific surface area of the oxynitride is 35 m(2) g(-1).

  • 出版日期2017-1