A fast metal-metal bonded water oxidation catalyst

作者：Goberna Ferron Sara; Pena Bruno; Soriano Lopez Joaquin; Carbo Jorge J; Zhao Hanhua; Poblet Josep M^*; Dunbar Kim R; Ramon Galan Mascaros Jose

来源：Journal of Catalysis, 2014, 315: 25-32.

DOI：10.1016/j.jcat.2014.04.010

• Water oxidation
• Metal-metal bonded compounds
• Ru catalyst
• Computational methods

The metal-metal bonded diruthenium (II,II) tetraacetate compound, [Ru-2(mu-O2CCH3)(4)], is a water oxidation catalyst (WOC) that exhibits oxygen evolution rates as high as 77 s(-1) at ambient conditions, exhibiting comparable catalytic activity over a wide pH range (1 < pH < 10). The turnover conditions of the catalyst remain active for several hours with oxidative deactivation eventually occurring at a slow rate. DFT calculations support a single-site mechanism via water nucleophilic attack, with the most energy demanding process being the very first one electron oxidation step. This is one of the fastest WOCs reported, and the first WOC found in the field of metal-metal bonded chemistry.

• 出版日期2014-6