A STUDY ON THE PHOSPHORYLATION OF INDOLE, IMIDAZOLE, CARBAZOLE, AND PHENOTHIAZINE DERIVATIVES

作者:Milen Matyas; Abranyi Balogh Peter; Balogh Gyoergy; Drahos Laszlo; Keglevich Gyoergy*
来源:Phosphorus, Sulfur, and Silicon and the Related Elements, 2012, 187(9): 1091-1100.
DOI:10.1080/10426507.2012.668986

摘要

N-Heterocycles including indolecarbaldehyde, substituted benzimidazoles, and methylimidazole could be efficiently phosphorylated by diethyl chlorophosphate at room temperature in different solvents using alkali carbonate or triethylamine as the base. However, the phosphorylation of N-heterocycles with a lower reactivity at the NH function, such as carbazole and phenothiazine, could not be conducted to complete conversion under the conditions applied.

  • 出版日期2012