N-heterocyclic carbene platinum complexes functionalized with a polyether chain and silyl group: Synthesis and application as a catalyst for hydrosilylation

作者：Zhang, Fengxiang; Bai, Ying^*; Yang, Xiaoling; Li, Jiayun; Peng, Jianjian^*

来源：Phosphorus, Sulfur, and Silicon and the Related Elements, 2017, 192(12): 1271-1278.

DOI：10.1080/10426507.2017.1321647

• N-heterocyclic carbene
• platinum
• hydrosilylation

The synthesis and characterization of new N-heterocyclic carbene platinum(II) complexes functionalized with a polyether chain and silyl group are described. In addition, their application towards the catalytic hydrosilylation of unsaturated carbon-carbon bonds, including alkenes, alkynes, vinyl ether, and unsaturated esters, is reported. These new complexes exhibit both excellent catalytic activity and selectivity for hydrosilylation. The catalytic system can be recycled >27times.

• 出版日期2017
• 单位杭州师范大学