Unexpected activity of novel 9-oxabispidine zinc complexes in lactide polymerization

作者：Borner Janna; Florke Ulrich; Doring Artjom; Kuckling Dirk; Jones Matthew D; Steiner Melanie; Breuning Matthias^*; Herres Pawlis Sonja

来源：Inorganic Chemistry Communications, 2010, 13(3): 369-371.

DOI：10.1016/j.inoche.2009.12.024

• 9-oxabispidines
• Chiral diamine
• Polylactide
• Ring-opening polymerization
• X-ray diffraction

The zinc dichlorido and zinc diacetato complexes of the chiral tricyclic 9-oxabispidine (1R,2S,9S)-11-methyl-13-oxa-7,11-diazatricyclo [7 3 1 0(27)] tridecane were prepared and characterized by X-ray crystallography.

• 出版日期2010-3