New Cd(II), Zn(II) helical coordination polymers constructed from hybrid ligands 4-ferrocenylbutyrate and 1,1-(1,4-butanediyl)bis-1H-benzimidazole

作者：Liu Shuangliang; Yang Yu; Qi Yongfang; Meng Xiangru; Hou Hongwei^*

来源：Journal of Molecular Structure, 2010, 975(1-3): 154-159.

DOI：10.1016/j.molstruc.2010.04.013

• Coordination polymers
• Crystal structure
• Electrochemical property
• 4-Ferrocenylbutyrate
• 1,1-(1,4-Butanediyl)bis-1H-benzimidazole

Self-assemblies of Cd(II) or Zn(II) salts with hybrid ligands sodium 4-ferrocenylbutyrate and 1,1-(1,4-butanediyl)bis-1H-benzimidazole (bbbm) gave rise to two new coordination polymers ([Cd(eta(2)-OOC(CH(2))(3)Fc)(2)(bbbm)]center dot CH(3)OH}(n) (1) and {[Zn(OOC(CH(2))(3)Fc)(eta(2)-OOC(CH(2))(3)Fc)(bbbm)]center dot CH(3)OH}(n) (2) (Fe = (eta(5)-C(5)H(5)) Fe(eta(5)-C(5)H(4))). Both polymers possess 1D helical chain structures with 21 screw axes along the b-direction although the coordination modes of the 4-ferrocenylbutyrate ligands and the coordination environments of the central metals in the two polymers are different. In addition, the redox properties of polymers 1 and 2 are also investigated and the results show that the formal potentials and the self-diffusion coefficients of the two polymers are close to each other.

• 出版日期2010-6-30
• 单位郑州大学; 中原工学院