A thermodynamic investigation on quenching mechanisms of the singlet and triplet state riboflavin by dopamine

作者：Ji Hong Fang; Shen Liang^*

来源：Journal of Molecular Structure (Theochem), 2008, 862(1-3): 148-150.

DOI：10.1016/j.theochem.2008.05.003

• dopamine
• riboflavin
• excited state
• quenching mechanism
• density functional theory

The quenching mechanisms of both the singlet and triplet state riboflavin (RF) by dopamine (DP) were investigated by means of density functional theory calculations in this communication. It was found that both the direct electron transfer and H-atom transfer pathways are thermodynamically feasible for the singlet state RF quenching by DP, while only the H-atom transfer pathway is involved in the triplet state RF quenching by DP.

• 出版日期2008-8-15
• 单位山东理工大学; 上海生物信息技术研究中心