A copper(II)-gadolinium(III) heterometallic MOF: Synthesis, structure, and electrochemical property

作者：Yin, Jia-Cheng; Qin, Tian-Zhu; Hu, Chao; He, Gui-Mei; Zhao, Bo-Wei; Zhang, Chi^*; Wang, Juan^*

来源：Materials Letters, 2017, 197: 221-223.

DOI：10.1016/j.matlet.2017.02.022

• Crystal structure
• Heterometallic MOF
• Hydrothermal synthesis
• Metallo-ligand
• Electrical properties

A heterometallic MOF [GdCu2(pydc)(3)(phen)(4)I(H2O)] (pydc = pyridine-2,6-dicarboxylate, phen = 1,10-phenanthroline) (1, CCDC 1429233) has been synthesized hydrothermally. In compound 1, the metalloligand [Gd(pydc)(3)] assembly with [Cu(phen)(2)] units to construct a hexanuclear cluster via Cu-O bonds and pi...pi interaction. The clusters are further stacked into a 3D supramolecular framework with cavities. The cyclic voltammogram shows an irreversible peak for Cu-II -> Cu-I reduction and a quasi-reversible peak for the couple Cu-II/Cu-III. Its optical and thermal properties have been investigated as well.

• 出版日期2017-6-15
• 单位湖北大学