Aqua[4-chloro-2-(2-pyridylmethyliminomethyl)phenolato]copper(II) nitrate monohydrate

作者:Liang Qing; Chen Xiaodan; Zhang Huaihong; Zou Zhihong*
来源:Acta Crystallographica Section E-Structure Reports Online, 2010, 66(1): M40-U491.
DOI:10.1107/S1600536809052350

摘要

In the title mononuclear complex, [Cu(C(13)H(10)ClN(2)O)(H(2)O)]NO(3)center dot H(2)O, the Cu(II) atom is four-coordinated by two N atoms and one O atom of the tridentate Schiff base ligand and one O atom from the coordinated water molecule in a slightly distorted square-planar configuration. The nitrate ion interacts with the copper center [Cu1 center dot center dot center dot O(3) = 2.579 (4) angstrom]. In the crystal, the cations, anions and water molecules are linked by O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds.

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