Non-oxidative Ethane Dehydroaromatization on Co/H-ZSM-5 Catalyst

作者:Saito Hikaru; Terunuma Ryota; Kojima Kiria; Yabe Tomohiro; Ogo Shuhei; Hirayama Haruaki; Tanaka Yukio; Sekine Yasushi*
来源:Chemistry Letters, 2017, 46(11): 1646-1649.
DOI:10.1246/cl.170688

摘要

Non-oxidative ethane dehydroaromatization to form aromatic hydrocarbons was investigated over various metal supported on H-ZSM-5 catalysts. Co/H-ZSM-5 prepared using an ion-exchange (IE) method exhibited high catalytic performance with a small amount of carbon deposition. Results obtained from temperature-programmed reduction and X-ray absorption fine structure spectroscopy indicate that stable Co2+ cations exist on Co/H-ZSM-5 IE during the reaction. Co2+ cations efficiently activate ethane without coke formation.

  • 出版日期2017-11