An S=12 semiquinoid radical-bridged Mn-6 wheel complex assembled from an asymmetric redox-active bridging ligand

作者：Jeon Ie Rang; Harris T David^*

来源：Chemical Communications, 2016, 52(5): 1006-1008.

DOI：10.1039/c5cc08482b

The asymmetric redox-active ligand 4,5-bis(pyridine-2-carboxamido)-1,2-catechol ((LH4)-L-N,O) is prepared and metalated to afford the hexanuclear complex [Mn-6(L-N,L-O)(6)](6-). Structural analysis and magnetic measurements reveal this complex to feature Mn-II ions bridged by L-N,O(3-center dot) radicals, which are antiferromagnetically coupled to give an S = 12 ground state.

• 出版日期2016
• 单位西北大学