A New Two-Dimensional Coordination Polymer Based on Trinuclear [Cd-3(COO)(6)] Clusters: Synthesis, Structure, and Luminescence

作者：Kang Xin Ping; An Zhe^*

来源：Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2015, 45(9): 1352-1355.

DOI：10.1080/15533174.2013.862709

• Cd(II) compound
• 2-aminoterephthalic acid
• trinuclear cluster
• luminescence

A new Cd(II) coordination polymer, namely {Cd-3(atpt)(3)(DMF)(2)[(CH3)(2)NH](2)}(n) (1 H(2)atpt = 2-aminoterephthalic acid, DMF = N,N'-dimethylformamide), has been synthesized by the reactions of Cd(II) ions with H(2)atpt in N,N-dimethylformamide (DMF) solution. Single-crystal X-ray analysis reveals that 1 features a two-dimensional (2D) layer framework based on linear trinuclear [Cd-3(COO)(6)] clusters. In addition, the luminescent property of 1 was also investigated in the solid state at room temperature.

• 出版日期2015
• 单位广东石油化工学院