A new approach to construct three dimensional segregated graphene structures in rubber composites for enhanced conductive, mechanical and barrier properties

作者：Lin, Yong; Liu, Shuqi; Liu, Lan^*

来源：Journal of Materials Chemistry C, 2016, 4(12): 2353-2358.

DOI：10.1039/c5tc04376j

• ELECTRICAL-CONDUCTIVITY
• POLYMER COMPOSITES
• NANOCOMPOSITES
• NANOPLATELETS
• MORPHOLOGY
• NETWORKS
• SENSORS
• OXIDE

Styrene butadiene rubber/graphene (SBR3GE-DH) composites with a segregated graphene network, synchronously having high electrical conductivity, mechanical strength and gas barrier properties, were fabricated for the first time using a pre-construction strategy combined with static hot pressing. A "three dimensional graphene (3D-GE) network'' with percolation conductive paths was efficiently constructed with an extremely low percolation threshold of 0.55 vol%. Remarkably, a conductivity of 0.033 S m(-1) at a 3D-GE content of 1.66 vol% was 8 orders of magnitude higher than that of the sheet-like GE-based composites (SBRGE) prepared by conventional latex compounding. All those outstanding properties were attributable to the well-constructed "3D-GE segregated networks'' in the SBR matrix and the strong interfacial adhesion between 3D-GE and the SBR matrix resulting from the geometric confinement of 3D-GE networks. Such performances make SBR3GE-DH composites very competitive for potential applications in high conductive sealing gaskets in the aerospace industry, sealed packages, and gas transport and storage devices.

• 出版日期2016
• 单位华南理工大学