A three-dimensional organic-inorganic 3d-4f hybrid polymer constructed with organic pyridinedicarboxylic acid and inorganic lanthanide sulfate skeletons

作者：Li Zhao Hao; Xue Li Ping^*; Miao Shao Bin; Zhao Bang Tun

来源：Inorganic Chemistry Communications, 2011, 14(10): 1690-1694.

DOI：10.1016/j.inoche.2011.07.008

• Pyridine-3,5-dicarboxylate
• Hydrothermal synthesis
• 3d-4f hybrid polymer
• Luminescent property

One 3d-4f heterometallic polymer, namely, {[Eu2Cu(PDC)(2)(SO4)(2)(H2O)(6)]center dot 2H(2)O}(n) (H2PDC = pyridine-3,5-dicarboxylic acid), has been successfully synthesized under hydrothermal conditions and structurally characterized. Single-crystal X-ray diffraction analysis reveals that the polymer features an unusual three-dimensional network structure in which infinite lanthanide-carboxylate chains are linked by [Cu(SO4)(2)](2-) metalloligands to form a mixed-metal coordination network. Furthermore, luminescent property of the hybrid material has also been investigated at room temperature.

• 出版日期2011-10
• 单位洛阳师范学院