μ-Succinato-bis[aqua(2,2′:6′,2"-terpyridine)copper(II)] dinitrate dihydrate

作者:Mei, Chongzhen*; Lei, Qingduo; Zhang, Peng
来源:ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66: M346-U3960.
DOI:10.1107/S1600536810006811

摘要

The title compound, [Cu-2(C4H4O4)(C15H11N3)(2)(H2O)(2)](NO3)(2)center dot 2H(2)O, was synthesized under hydrothermal conditions. The dinuclear copper complex is located on a crystallographic inversion centre. The Cu-II ion is pentacoordinated in a tetragonal-pyramidal geometry, with one O atom of a succinate dianion and three N atoms of a 2,2':6',2 ''-terpyridine ligand occupying the basal plane, and a water O atom located at the apical site. In the crystal structure, O-H center dot center dot center dot O hydrogen bonding links the molecules into a chain parallel to the a axis.