A three-dimensional supramolecular vanadium hydroxylamide complex: poly[di-mu(2)-aqua-bis(hydroxylamido)-mu(3)-malonato-oxidosodiumvanadium (V)]

作者：Zhang Qi Ying; Zhang Heng Qiang; Kong Ai Guo; Yang Qian; Shan Yong Kui^*

来源：Acta Crystallographica Section C-Crystal Structure Communications, 2009, 65(10): M401-M403.

DOI：10.1107/S0108270109036300

The crystal structure of the title compound, [NaV-(C3H2O4)(NH2O)(2)O(H2O)(2)], is built up of NaO6 and VO5N2 polyhedra connected through malonate bridges. The NaO6 octahedra are linked by edge sharing in the equatorial plane to form one-dimensional infinite chains. These chains are linked together by the malonate bridges to form two-dimensional layers. The distorted VO5N2 pentagonal bipyramid is grafted on to the layer by a malonate carboxylate O atom. Adjacent layers are connected through O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds to build up a three-dimensional supra-molecular structure.

• 出版日期2009-10
• 单位华东师范大学