A new organic-inorganic molybdenum arsenate complex based on [(CuO6)(As3O3)(2)Mo6O18](4-) cluster as secondary building units

作者：Su Fangyong; Zhou Baibin^*; Zhao Zhifeng; Su Zhanhua; Zhu Chuncheng

来源：Crystal Research and Technology, 2009, 44(4): 447-452.

DOI：10.1002/crat.200800542

• molybdenum arsenate
• copper-complex
• electrochemical properties

A new molybdenum arsenate, [Cu(imi)(2)](2)[(CuO6)(As3O3)(2)Mo6O18][Cu(imi)(2)](2) (1) (imi = C3N2H4), has been synthesized under mild hydrothermal conditions, and characterized by elemental analysis, IR, thermogravimetric analyses, and single-crystal X-ray diffraction analysis. The polyanion framework derives from the Anderson structure in which the central octahedron is filled up by a copper (II), and is capped on both sides by two cyclic As3O6 groups. The countercations contain bisupported [Cu(imi)(2)](+) Complex cations and two free [Cu(imi)(2)](+) complex cations. The electrochemical behavior of 1-modified carbon paste electrode (1-CPE) has been studied in detail.

• 出版日期2009-4
• 单位哈尔滨工业大学; 哈尔滨师范大学