Aqua{6,6 '-dimethoxy-2,2 '-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)

作者：Guo Zhenghua; Li Lianzhi^*; Xu Tao; Li Jinghong; Wang Daqi

来源：Acta Crystallographica Section E-Structure Reports Online, 2009, 65(10): M1158-+.

DOI：10.1107/S1600536809034278

The title complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], lies on a mirror plane with the Ni(II) ion coordinated by two N and two O atoms of a tetradentate Schiff base ligand and one water O atom in a distorted square-pyramidal enviroment. The -CH(2)-CH(2)- group of the ligand is disordered equally over two sites about the mirror plane. The dihedral angle between the mean planes of the two symmetry-related chelate rings is 37.16 (6)degrees. In the crystal structure, intermolecular O-H center dot center dot center dot O hydrogen bonds link complex molecules into one-dimensional chains along [100] and these chains are linked, in turn, by very weak intermolecular C-H center dot center dot center dot O hydrogen bonds into a two-dimensional network.

• 出版日期2009-10
• 单位聊城大学