A cis-dioxomolybdenum Schiff base complex: synthesis, crystal structure and catalytic activity in oxidation of olefins using hydrogen peroxide

作者：Tadayonpour Nasim; Rayati Saeed^*; Sadr Moayad Hossaini; Zare Karim; Wojtczak Andrzej

来源：Transition Metal Chemistry, 2015, 40(8): 891-897.

DOI：10.1007/s11243-015-9985-3

A cis-dioxomolybdenum(VI) Schiff base complex [MoO2L] has been synthesized and structurally characterized. Homogeneous oxidation of olefins using the complex as a catalyst with hydrogen peroxide as oxidant in ethanol solution showed high catalytic activity for this complex. Under reflux conditions, the oxidation of cyclooctene, styrene, alpha-methyl styrene, 4-methyl styrene and 1-methyl cyclohexene with hydrogen peroxide gave the corresponding epoxides as the sole products.

• 出版日期2015-11