A Fixed-Bed Reactor Study of Catalytic Partial Oxidation over Rh/Al2O3: An Indication of a Direct Pathway to CO

作者：Lodeng Rune^*; Bjorgum Erlend; Enger Bjorn Christian; Eilertsen Jan Lasse; Holmen Anders; Krogh Bente; Boe Ingrid Aartun; Ronnekleiv Morten; Rytter Erling

来源：Topics in Catalysis, 2011, 54(13-15): 873-880.

DOI：10.1007/s11244-011-9693-y

• Catalytic partial oxidation
• Methane
• Hydrogen
• Synthesis gas
• Rhodium

Catalytic partial oxidation (CPO) of CH4 in air was investigated over Rh/Al2O3 catalysts (0.01, 0.05, 0.1 and 1 wt% Rh-0) in co-feed modus in laboratory scale fixed-bed reactors. Main focus was on catalyst stability and selectivity at low temperatures (<700 degrees C). A particularly high selectivity to CO was observed, indicating existence of a direct pathway.

• 出版日期2011-9