A novel high energy density flexible galvanic cell

作者：Peckerar Martin^*; Dilli Zeynep; Dornajafi Mahsa; Goldsman Neil; Yves Ngu; Proctor Robert B; Krupsaw Benjamin J; Lowy Daniel A

来源：Energy & Environmental Science, 2011, 4(5): 1807-1812.

DOI：10.1039/c1ee01075a

Ultrathin galvanic cells, which can comply with a variety of form factors and electronic system packages, are of technological importance, as they show promise for flexible electronic systems. Here we describe a high energy density flexible galvanic cell, which is non-toxic and environmentally friendly. It operates with a zinc anode and hydrated ruthenium(IV) oxide cathode, where RuO(2)center dot nH(2)O nanoparticles are utilized in amounts that are not cost-prohibitive. As the battery utilizes aqueous electrolytes, it is safe in operation, which enables its use in a number of settings and surroundings. It can be optimized for volume manufacture at low cost. Given that they function at much lower cell voltage than Li-ion batteries do, Zn-RuO(2)center dot nH(2)O cells can be recharged remotely, at a conveniently low voltage, by harvesting, for example, radio-frequency (RF) energy or microwaves. As an additional asset, Zn-RuO(2)center dot nH(2)O electrodes enable battery-supercapacitor hybrid power sources. At present, this cell demonstrates a specific charge capacity of 84.4 mAh per cm(2) of projected electrode area, which is, so far, the largest value reported for thin film cells. Also, its cycle life of up to 400 charge-discharge cycles is very promising for use as a secondary battery.

• 出版日期2011-5