A new one-dimensional Cd-II complex, [Cd(mu(2)-L)(2)](n) (HL=3-(2-pyridyl)-pyrazole) with planar [Cd(mu(2)-L)(2) unit: synthesis, crystal structure and emission property

作者：Hu Tong Liang; Wang Jun Jie; Li Jian Rong; Bu Xian He^*

来源：Journal of Molecular Structure, 2006, 796(1-3): 18-22.

DOI：10.1016/j.molstruc.2005.12.027

• Cd-II complex
• crystal structure
• hydrothermal synthesis
• 3-(2-pyridyl)pyrazole
• luminescence

A new one-dimension complex, [Cd(mu-L)(2)](n), (1, HL=3-(2-pyridyl)pyrazole), has been hydrothermally synthesized and characterized by elemental analysis, IR, TGA, and single-crystal X-ray diffraction analysis. In 1, the L ligand takes tridentate chelating-bridging coordination mode via deprotonation of the pyrazolyl NH group and coordination of the pyrazolyl N atom to a second metal ion. In the solid state, complex 1 shows blue photoluminescent property at room temperature.

• 出版日期2006-8-30
• 单位南开大学