PALLADIUM CATALYZED INTRAMOLECULAR VINYLSELENATION AND VINYLTHIOLATION OF ALLENES

作者：Tsuda Susumu; Okuyama Maiko; Fujiwara Shin ichi^*; Iwasaki Takanori; Kuniyasu Hitoshi; Kambe Nobuaki

来源：Heterocycles, 2015, 90(2): 1323-1331.

DOI：10.3987/COM-14-S(K)80

Intramolecular vinylselenation of allenes 1a,b proceeds in the presence of Pd(0) catalyst producing pyridin-2-one derivatives 2a,b having a high degree of unsaturation as a sole product. This cyclization could also be applied to vinylthiolation and to the construction of seven-membered lactams.

• 出版日期2015-1-1