Ammonia-Rich High-Temperature Superconducting Intercalates of Iron Selenide Revealed through Time-Resolved in Situ X-ray and Neutron Diffraction

作者:Sedlmaier Stefan J; Cassidy Simon J; Morris Richard G; Drakopoulos Michael; Reinhard Christina; Moorhouse Saul J; O'Hare Dermot; Manuel Pascal; Khalyavin Dmitry; Clarke Simon J*
来源:Journal of the American Chemical Society, 2014, 136(2): 630-633.
DOI:10.1021/ja411624q

摘要

The development of a technique for following in situ the reactions of solids with alkali metal/ammonia solutions, using time-resolved X-ray diffraction methods, reveals high-temperature superconducting ammonia-rich intercalates of iron selenide which reversibly absorb and desorb ammonia around ambient temperatures.

  • 出版日期2014-1-15