Anomalous piezoelectricity in two-dimensional graphene nitride nanosheets

作者：Zelisko Matthew; Hanlumyuang Yuranan; Yang Shubin; Liu Yuanming; Lei Chihou; Li Jiangyu; Ajayan Pulickel M; Sharma Pradeep^*

来源：Nature Communications, 2014, 5(1): 4284.

DOI：10.1038/ncomms5284

Piezoelectricity is a unique property of materials that permits the conversion of mechanical stimuli into electrical and vice versa. On the basis of crystal symmetry considerations, pristine carbon nitride (C3N4) in its various forms is non-piezoelectric. Here we find clear evidence via piezoresponse force microscopy and quantum mechanical calculations that both atomically thin and layered graphitic carbon nitride, or graphene nitride, nanosheets exhibit anomalous piezoelectricity. Insights from ab inito calculations indicate that the emergence of piezoelectricity in this material is due to the fact that a stable phase of graphene nitride nanosheet is riddled with regularly spaced triangular holes. These non-centrosymmetric pores, and the universal presence of flexoelectricity in all dielectrics, lead to the manifestation of the apparent and experimentally verified piezoelectric response. Quantitatively, an e(11) piezo-electric coefficient of 0.758 Cm-2 is predicted for C3N4 superlattice, significantly larger than that of the commonly compared alpha-quartz.

• 出版日期2014-6