A 3D luminescent Zn(II) coordination polymer with rutile-type topology

作者:Wu, Jian; Liu, Jian-Qiang*; Wang, Fu-min; Wu, Tie; Jun, Wang
来源:Inorganic Chemistry Communications, 2013, 31: 87-89.
DOI:10.1016/j.inoche.2013.03.010

摘要

A new coordination network, namely {[Zn(bce)(H2O)]}(n) (1) (H(2)bce = 1,2-bis(4-carboxy-phenoxy)ethane), is reported. complex 1 shows a 3D (3,6)-connected rutile (rtl) topology. The luminescence study indicates that the title compound emits bright green fluorescence and possesses moderate fluorescence lifetimes (tau = 2.26 ns).