A highly rare (3,4,5,6)-connected metal-organic framework containing three distinct Co-2 secondary building units

作者：Luo Feng^*; Ning Yang; Tong Xiao lan; Luo Ming biao

来源：Inorganic Chemistry Communications, 2010, 13(5): 671-675.

DOI：10.1016/j.inoche.2010.03.016

• MOF
• Multi-nodal framework
• Porous materials
• Phase transition

Via solvothermal reaction of CoCl2 with H3BTC (1,3,5-benzenetricarboxylic acid) in DMF-C2H5OH, a new metal-organic framework (MOF) was isolated. The single crystal X-ray diffraction suggests that the asymmetric unit contains six crystallography-independent Co(II) ions and four deprotonated BTC3- ligands, and the overall structure of it is a 3D microporous framework with three-dimensional intersecting channel. Further topological analysis reveals a highly rare (3, 4, 5, 6)-connected net.

• 出版日期2010-5
• 单位东华理工大学