Asymmetric Alkylation of N-Sulfonylbenzamides with Vinyl Ethers via C-H Bond Activation Catalyzed by Hydroxoiridium/Chiral Diene Complexes

作者:Hatano Miyuki; Ebe Yusuke; Nishimura Takahiro*; Yorimitsu Hideki
来源:Journal of the American Chemical Society, 2016, 138(12): 4010-4013.
DOI:10.1021/jacs.6b01591

摘要

Asymmetric alkylation of N-sulfonylbenzamides with vinyl ethers via a directed C-H bond activation gave high yields of the corresponding addition products with high branch- and enantioselectivity.

  • 出版日期2016-3-30