Manipulating the Torsion of Molecules by Strong Laser Pulses

作者:Madsen C B; Madsen L B*; Viftrup S S; Johansson M P; Poulsen T B; Holmegaard L; Kumarappan V; Jorgensen K A; Stapelfeldt H
来源:Physical Review Letters, 2009, 102(7): 073007.
DOI:10.1103/PhysRevLett.102.073007

摘要

We demonstrate that strong laser pulses can induce torsional motion in a molecule consisting of a pair of phenyl rings. A nanosecond laser pulse spatially aligns the carbon-carbon bond axis, connecting the two phenyl rings, allowing a perpendicularly polarized, intense femtosecond pulse to initiate torsional motion accompanied by an overall rotation about the fixed axis. We monitor the induced motion by femtosecond time-resolved Coulomb explosion imaging. Our theoretical analysis accounts for and generalizes the experimental findings.

  • 出版日期2009-2-20