Dynamic Impact of RuCl3 Catalyst on the Oxidation of Cyclamate with Acidified Bromamine-T: Elucidation of Mechanistic Pathways and Kinetic Modeling

作者：Radhakrishnan Ramya; Puttaswamy^*

来源：Catalysis Letters, 2017, 147(6): 1392-1402.

DOI：10.1007/s10562-017-2034-4

• RuCl3-catalysis
• Cyclamate
• Bromamine-T
• Oxidation-kinetics
• Mechanism
• Activation parameters

Oxidation-Kinetics of cyclamate by bromamine-T (BAT) in HClO4 medium catalyzed by RuCl3 exhibits a first-order dependence on [BAT](0), fractional-order on both [Cyclamate](0) and [RuCl3], and inverse fractional-order on [HClO4]. RuCl3 catalyst accelerated the reaction by a splendid 48 times. Plausible mechanism and related rate law have been deduced.
The Stoichiometry of the reaction is:.

• 出版日期2017-6