科研之友
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摘要
The selective and simultaneous production of hydrogen and chemicals from renewable alcohols was accomplished by using an electrolyzer, for which the anode electrocatalyst was an organometallic complex, [Rh(OTf)(trop(2)NH){P(4-BuC6H4)(3)}](trop(2)NH=bis(5H-dibenzo[a,d]cyclohepten-5-yl)amine; -OTf=CF3SO3-), deposited on amorphous carbon and appropriately designed to promote the partial and selective oxidation of alcohols. The electrolyzer converted alcohols into industrially relevant chemicals and high-purity hydrogen at high volume and with very low energy consumption.
- 出版日期2017-3
- 单位浙江大学
