A naphthalene diimide-based MOF with mog net featuring photochromic behaviors and high stability

作者：Wei, Fangfang; Ye, Yingxiang; Huang, Wenhuan; Lin, Quanjie; Li, Ziyin; Liu, Lizhen; Chen, Shimin; Zhang, Zhangjing^*; Xiang, Shengchang^*

来源：Inorganic Chemistry Communications, 2018, 93: 105-109.

DOI：10.1016/j.inoche.2018.05.011

• Metal-organic framework
• mog topology
• Photochromism
• Chemical stability

A novel photochromic metal-organic framework (Zn(L)(0.5)(bpy)(H2O)]center dot 3.5H(2)O, FJU-34) based on Zn(II), carboxylate-based naphthalene diimides derivatives (H4L) and 4,4'-bipyridine (bpy) has been prepared, which exhibits a unique doubly interpenetrated 3D open framework with a rare mog topological net. In addition, the excellent chemical stability and reversible photochromic performances have been observed in this compound.

• 出版日期2018-7
• 单位福建师范大学