An unusual chain constructed from heteropolyanions and isopolyanions: [{Cu(2,2 '-bipy)}(6)(Mo6O22)][SiMo12O40]

作者：Zhang, Chun-Jing; Zhang, Chun-Hua; Pang, Hai-Jun; Wang, Da-Peng; Kong, Qing-Jiao; Yang, Xiao-Dan; Yao, Feng; Tang, Qun; Wang, Hui-Yuan; Chen, Ya-Guang^*

来源：Solid State Sciences, 2010, 12(2): 281-283.

DOI：10.1016/j.solidstatesciences.2009.11.008

• Polyoxometalates
• Organic-inorganic hybrid
• Heteropolyanion
• Isopolyanion
• Copper

A new compound based on transition metal complexes modified heteropolyanions and isopolyanions: [{Cu(2,2'-bipy)}(6)(Mo6O22)][SiMo12O40] (1) (2,2'-bipy = 2,2'-bipyridine), has been hydrothermally synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. In compound 1, each of the [Mo6O22](8-) clusters is surrounded by six {Cu(2,2'-bipy)}(2+) fragments forming [{Cu(2,2'-bipy)}(6)(Mo6O22)](4+) cations which further alternately link the [SiMo12O40](4) anions to result in an unusual 1D chain.

• 出版日期2010-2
• 单位白城师范学院; 东北师范大学