Unprecedented alpha-Octamolybdate Derivative Containing Hexad-track Cu-bpe Chains, 2{[Cu(bpe)]6[alpha-Mo8O26](3/2)}center dot[Cu(bpe)](3)center dot 3H(2)O

作者：Sha Jing-quan; Li Xin; Peng Jun^*; Zong Xi-ming; Zhang Yu-hong; Yan Hong

来源：Chemical Research in Chinese Universities, 2011, 27(2): 166-169.

• Octamolybdate
• Hydrothermal synthesis
• Multi-track chain
• Electrochemical property

A new inorganic-organic hybrid constructed from alpha-octamolybdate polyoxometalates modified by hexad-track Cu-bpe chains, 2{[Cu(bpe)](6)[alpha-Mo8O26](3/2)}center dot[Cu(bpe)](3)center dot 3H(2)O[1, bpe=bis(4-pyridyl)ethylene], has been synthesized and structurally characterized. X-Ray diffraction analysis reveals that each a-octamolybdate cluster links six transition metal complex chains and the title compound has represented the highest connective number of M-N chains modified octamolybdate POMs to date. Note that there are two crystallographically unique [alpha-Mo8O26](n-) clusters and eight unique copper sites, which play an important role in the overall architecture of hybrid compounds. Additionally, the electrochemical properties of the title compound were studied.

• 出版日期2011-3
• 单位佳木斯大学; 东北师范大学