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摘要
Poly[tin(II)-mu -phenylphosphonato], [Sn(C6H5O3P)](n), was synthesized solvothermally at 423 K and crystallized in the monoclinic system, space group Cc. The inorganic layers consist of alternating pyramidal Sn and tetrahedral P centers, joined by doubly bridging O atoms. The corner-sharing SnO3 and PO3C6H5 polyhedra define a corrugated layer of six-membered rings. The layers are connected along the unique b axis by interdigitated phenyl rings of the phenylphosphonate groups.
- 出版日期2001-9
