Asymmetric transformation by dynamic crystallization of achiral succinimides

作者:Hachiya Shoko; Kasashima Yoshio; Yagishita Fumitoshi; Mino Takashi; Masu Hyuma; Sakamoto Masami*
来源:Chemical communications, 2013, 49(42): 4776-4778.
DOI:10.1039/c3cc41678j

摘要

Optically active materials could be generated by simple solidification of achiral materials without an external chiral source. When achiral cis-3,4-diphenylsuccinimides were solidified in the presence of a catalytic amount of DBU by evaporating the solvent with stirring, optically active trans-3,4-diphenylsuccinimides were obtained quantitatively with high enantiomeric excesses.

  • 出版日期2013