科研之友
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摘要
This report describes rapid photoisomerization of a lophine dimer facilitated by the inner environment of molecular assemblies. When the dimer was solubilized in a micellar solution, the rate of recombination of lophyl radicals, which were produced by ultraviolet irradiation, accelerated 100-fold. This result suggests that the confined space provided by the micelles inhibits free diffusion of the radical species and remarkably enhances the isomerization rate.
- 出版日期2018
