Novel molybdenum complexes with the 3,6-Di-tert-butylcatecholate ligand

作者：Petrov P A^*; Afonin M Yu; Naumov D Yu; Konchenko S N; Piskunov A V

来源：Russian Journal of Coordination Chemistry, 2015, 41(1): 31-36.

DOI：10.1134/S1070328415010078

A reaction of the cluster (Et4N)(2)[Mo3S7Br6] with potassium 3,6-di-tert-butyl-o-benzosemiquinolate (KSQ(36)) afforded the mononuclear complexes (Et4N)[Mo(Cat(36))(3)] (I) and (Et4N)[MoO(Cat(36))(2)(HCat(36))] (II) with prismatic and octahedral environments of their central metal atoms, respectively. Complex I was also obtained by a reaction between MoCl5, sodium 3,6-di-tert-butylcatecholate (Na(2)Cat(36)), and Et4NBr. Complexes I and II were characterized by X-ray diffraction and EPR spectroscopy. The structures have been deposited with the Cambridge Structural Database (nos. 1009139 (I), 1009140 (I center dot 1.5THF), and 1009141 (II center dot Et2O)).

• 出版日期2015-1