A Polymer Network Prepared by the Thiol-yne Photocrosslinking of a Liquid Crystalline Dendrimer

作者:Cervera Procas Ramon; Sanchez Somolinos Carlos; Serrano Jose L*; Omenat Ana
来源:Macromolecular Rapid Communications, 2013, 34(6): 498-503.
DOI:10.1002/marc.201200730

摘要

A polymer network is prepared by the thiol-yne photopolymerization of multifunctional dendrimer with a tetrathiol crosslinker. The network obtained shows a liquid crystalline phase at room temperature, which has been characterized by optical microscopy, differential scanning calorimetry, and X-ray diffraction. Photoinduced deformation of uniaxially aligned free-standing films of the photocrosslinked material has been demonstrated.

  • 出版日期2013-3-25