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摘要
X80 steel has the potential to be widely used for building the gas transmission pipelines because of its high-intensity and high-toughness. its corrosion performance is a key problem for the life expectancy, especially in soil environment. The anodic electrochemical behavior of X80 pipeline steel in NaHCO3 solution was studied using potentiodynamic polarization curve dynamic electrochemical impedance spectroscopy (DEIS) as well as SEM observation. The results show that mm shape or mic polarization curves changes with HCO3- concentration The corrosion rate of X80 pipeline steel first increases mid then decreases with the increase of HCO3- concentration 0.009 mol/L is the critical concentration of HCO3- for forming the 'passive' film of the X80 pipeline steel There is no anodic current peak in the solution when HCO3- concentration is below 0.009 mol/L, and one anodic current peak below 0.05 mol/L and two anodic current peaks above 0.1 mol/L. The results of the DEIS measurements are in complete agreement with the potentiodynamic polarization curve The corrosion products change with polarization potential and two equivalent circuits are used to explain the experimental spectra of X80 pipeline steel in the whole corrosion process. Therefore, the combination of dynamic polarization curve and DEIS methods can be well used to investigate the corrosion behaviour of X80 pipeline steel in NaHCO3 solution at various potentials. In addition, different corrosion products forming at various potentials and the corrosion mechanisms of X80 pipeline steel are briefly analyzed.
- 出版日期2010-2-11
- 单位武汉材料保护研究所; 北京科技大学
