A new (RuRhIII)-Rh-II bimetallic with a single Rh-Cl bond as a supramolecular photocatalyst for proton reduction

作者：Zhou Rongwei; Manbeck Gerald F; Wimer Dexter G; Brewer Karen J

来源：Chemical Communications, 2015, 51(65): 12966-12969.

DOI：10.1039/c5cc04123f

Photoinitiated electron collection on the RhIII center bearing only one photo-labile Rh–Cl bond resulted in an active RuRhI species for proton reduction. The results opened a new approach to designing RuIIRhIII photocatalysts.

• 出版日期2015
• 单位美国弗吉尼亚理工大学(Virginia Tech)