科研之友
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摘要
GMZ bentonite has been selected as a potential material for the construction of engineered barrier in the Chinese program of geological nuclear waste disposal, for its high montmorillonite content, high cation exchange capacity (CEC) and large specific surface etc. Studies on mineralogy and chemical composition, mechanical properties, hydraulic behavior, swelling behavior, thermal conductivity, microstructure and volume change behavior of GMZ bentonite were performed from 1980s. Based on a review of the former studies, achievements on experimental and theoretic results obtained on compacted GMZ bentonite specimens including basic properties, thermal, hydraulic and mechanical behaviors are presented in this paper. Results show the thermal conductivity of GMZ bentonite and the bentonite-based mixtures influenced by its dry density, water content, mixture of other materials and degree of saturation etc. Water retention capacity of highly-compacted GMZ bentonite decreases as the temperature increases under confined and unconfined conditions. The hysteretic behavior in the water retention curves of the compacted GMZ bentonite is not so significant at 20 or 40 degrees C. The unsaturated hydraulic conductivity of compacted GMZ bentonite under unconfined conditions is higher than that of under confined conditions. This is possibly induced by the difference in the mechanism of microstructural changes during hydration under different confining conditions. The compaction curves for GMZ bentonite with different dry densities are clearly step-phased. And the optimum water content for GMZ bentonite is about 15%. An exponential relationship between swelling pressure and dry density of highly-compacted GMZ bentonite was determined for the prediction of swelling pressure. Furthermore, the void ratio after swelling for unconfined sample also can be predicted using diffuse double layer (DDL) theory.
