A one-pot synthesis of a paramagnetic high-nuclearity nickel(II) cluster: an octadecanuclear (Ni16Na2I)-Na-II metal aggregate

作者:Biswas Biplab; Khanra Sumit; Weyhermueller Thomas; Chaudhuri Phalguni*
来源:Chemical Communications, 2007, (10): 1059-1061.
DOI:10.1039/b613782b

摘要

An unusual (Ni16Na2I)-Na-II cluster which features formate as a bridging clamp between two octanuclear nickel cages is reported; preliminary magnetic studies exhibit paramagnetic low-lying states resulting from dominating antiferromagnetic interactions between the nickel(II) centers.

  • 出版日期2007