A new method for the synthesis of isothiocyanates from dithiocarbamates or alkyl amines using chlorosilanes as decomposition reagents

作者：Bian Gaofeng; Qiu Huayu; Jiang Jianxiong; Wu Jirong; Lai Guoqiao^*

来源：Phosphorus, Sulfur, and Silicon and the Related Elements, 2007, 182(3): 503-508.

DOI：10.1080/10426500600977379

• isothiocyanates
• chlorosilanes
• decomposition reagents
• Me3SiCl
• Me2SiCl2
• MeSiCl2
• SiCl4

A series of isothiocyanates were prepared in good yields by the decomposition of dithiocarbamates using chlorosilanes such as Me3SiCl, Me2SiCl2, MeSiCl3, and SiCl4 as decomposition reagents. Alkyl isothiocyanates were obtained by a facile one-pot method in high yield from alkyl amines using these inexpensive decomposition reagents in the presence of a base.

• 出版日期2007-3
• 单位杭州师范大学