Facile carbon-sulfur bond cleavage in diarylsulfonium ylides: a catalytic sulfur-to-silicon group transfer

作者：Huang Xueliang; Goddard Richard; Maulide Nuno^*

来源：Chemical communications, 2013, 49(39): 4292-4294.

DOI：10.1039/c2cc35762c

An unusual cleavage of the non-ylidic carbon-sulfur bond of a sulfonium ylide is reported. The reaction can be catalysed by a variety of palladium(II) complexes under mild conditions. Preliminary results show that coordination of the ylide to the metal center results in significant structural changes.

• 出版日期2013