Aerobic copper-catalyzed decarboxylative thiolation

作者:Li Minghao; Hoover Jessica M
来源:Chemical Communications, 2016, 52(56): 8733-8736.
DOI:10.1039/c6cc04486g

摘要

Copper-catalyzed decarboxylative thiolation using molecular oxygen as the sole oxidant was developed. A variety of aromatic carboxylic acids including 2-nitrobenzoic acids, pentafluorobenzoic acid and several heteroaromatic carboxylic acids undergo efficient thiolation to furnish the aryl sulfides in moderate to excellent yields.

  • 出版日期2016