Aerobic Photooxidative Synthesis of Secondary Aldimines from Benzylamines by Using Methylene Blue

作者：Okada Akifumi; Yuasa Hiroki; Fujiya Akitoshi; Tada Norihiro; Miura Tsuyoshi; Itoh Akichika^*

来源：Synlett, 2015, 26(12): 1705-1709.

DOI：10.1055/s-0034-1379923

• aerobic
• methylene blue
• photooxidation
• singlet oxygen
• primary amine
• imine

We have developed a concise oxidative coupling of primary benzylamines to yield secondary aldimines catalyzed by methylene blue by using molecular oxygen as the oxidant in the presence of visible-light irradiation from fluorescent lamps.

• 出版日期2015-7